Having used CAFS in anger at rural incidents - I'm sold! Having seen the Blackwood 24 CAFS at a rural incident I'm sold there two (providing their pump operator can keep it together lol). Having seen CAFS intersate and various versions for rural applications I sold here two. Also for bin fires, car fires and rubbish fire - sold!
However, where I'm not sold is the structural application. As already stated by Mattb, there is heaps on the net about it's use and some great papers on CAFS versus water particle attach (3d attach, fog attach and combination attack)however what isn't well written about is the effect the foam concentrate has in fire investigation. Several things to consider - the foam breaks down the hydrocarbon chain - hence had to collect the evidence, secondly the foam blanket takes a while to disperse - alternatively it needs to be wash away - both lead to deterioration of the evidence used to determine cause.
So horses for courses - excellent in the rural application and in non structural fires, but I'm not a fan for structural fires!